Instantaneous modulations in time-varying complex optical potentials

We study the impact of a spatially homogeneous yet non-stationary dielectric permittivity on the dynamical and spectral properties of light. Our choice of potential is motivated by the interest in ${ \mathcal P }{ \mathcal T }$-symmetric systems as an extension of quantum mechanics. Because we consider a homogeneous and non-stationary medium, ${ \mathcal P }{ \mathcal T }$ symmetry reduces to time-reversal symmetry in the presence of balanced gain and loss. We construct the instantaneous amplitude and angular frequency of waves within the framework of Maxwell's equations and demonstrate the modulation of light amplification and attenuation associated with the well-defined temporal domains of gain and loss, respectively. Moreover, we predict the splitting of extrema of the angular frequency modulation and demonstrate the associated shrinkage of the modulation period. Our theory can be extended for investigating similar time-dependent effects with matter and acoustic waves in ${ \mathcal P }{ \mathcal T }$-symmetric structures

Bessel beams of two-level atoms driven by a linearly polarized laser field

We study Bessel beams of two-level atoms that are driven by a linearly polarized laser field. Starting from the Schroedinger equation, we determine the states of two-level atoms in a plane-wave field respecting propagation directions both of the atom and the field. For such laser-driven two-level atoms, we construct Bessel beams beyond the typical paraxial approximation. We show that the probability density of these atomic beams obtains a non-trivial, Bessel-squared-type behavior and can be tuned under the special choice of the atom and laser parameters, such as the nuclear charge, atom velocity, laser frequency, and propagation geometry of the atom and laser beams. Moreover, we spatially and temporally characterize the beam of hydrogen and selected (neutral) alkali-metal atoms that carry non-zero orbital angular momentum (OAM). The proposed spatiotemporal Bessel states (i) are able to describe, in principle, twisted states of any two-level system which is driven by the radiation field and (ii) have potential applications in atomic, nuclear processes and quantum communication.Comment: 13 pages, 5 figures, appeared as a EPJD highlight on Thursday, 01 August 2013 http://www.epj.org/index.php?option=com_content&view=article&id=684%3Aepjd-highlight-novel-beams-made-of-twisted-atoms&catid=112%3Aepj-d&Itemid=466&lang=e

Nonuniform currents and spins of relativistic electron vortices in a magnetic field

We present a relativistic description of electron vortex beams in a homogeneous magnetic field. Including spin from the beginning reveals that spin-polarized electron vortex beams have a complicated azimuthal current structure, containing small rings of counterrotating current between rings of stronger corotating current. Contrary to many other problems in relativistic quantum mechanics, there exists a set of vortex beams with exactly zero spin-orbit mixing in the highly relativistic and nonparaxial regime. The well defined phase structure of these beams is analogous to simpler scalar vortex beams, owing to the protection by the Zeeman effect. For states that do show spin-orbit mixing, the spin polarization across the beam is nonuniform rendering the spin and orbital degrees of freedom inherently inseparable.Comment: 5 pages + supplemental materia

Instantaneous modulations in time-varying complex optical potentials

We study the impact of a spatially homogeneous yet non-stationary dielectric permittivity on the dynamical and spectral properties of light. Our choice of potential is motivated by the interest in PT-symmetric systems as an extension of quantum mechanics. Because we consider a homogeneous and non-stationary medium, PT symmetry reduces to time-reversal symmetry in the presence of balanced gain and loss. We construct the instantaneous amplitude and angular frequency of waves within the framework of Maxwell's equations and demonstrate the modulation of light amplification and attenuation associated with the well-defined temporal domains of gain and loss, respectively. Moreover, we predict the splitting of extrema of the angular frequency modulation and demonstrate the associated shrinkage of the modulation period. Our theory can be extended for investigating similar time-dependent effects with matter and acoustic waves in PT-symmetric structures.Comment: 13 pages, 4 figure

Atomic ionization by twisted photons: Angular distribution of emitted electrons

We investigate the angular distribution of electrons that are emitted in the ionization of hydrogen-like ions by twisted photons. Analysis is performed based on the first-order perturbation theory and the non-relativistic Schr\"odinger equation. Special attention is paid to the dependence of the electron emission pattern on the impact parameter b of the ion with respect to the centre of the twisted wave front. In order to explore such a dependence, detailed calculations were carried out for the photoionization of the 1s ground and 2 py excited states of neutral hydrogen atoms. Based on these calculations, we argue that for relatively small impact parameters the electron angular distributions may be strongly affected by altering the position of the atom within the wave front. In contrast, if the atom is placed far from the front centre, the emission pattern of the electrons is independent on the impact parameter b and resembles that observed in the photoionization by plane wave photons.Comment: 23 pages, 6 figure

Radiative Capture of Twisted Electrons by Bare Ions

Recent advances in the production of twisted electron beams with a subnanometer spot size offer unique opportunities to explore the role of orbital angular momentum (OAM) in basic atomic processes. In the present work, we address one of these processes: radiative recombination of twisted electrons with bare ions. Based on the density matrix formalism and the non-relativistic Schr\"odinger theory, analytical expressions are derived for the angular distribution and the linear polarization of photons emitted due to the capture of twisted electrons into the ground state of (hydrogen-like) ions. We show that these angular and polarization distributions are sensitive to both, the transverse momentum and the topological charge of the electron beam. To observe in particular the value of this charge, we propose an experiment that makes use of the coherent superposition of two twisted beams.Comment: 5 pages, 3 figure

Electromagnetic wave propagation in spatially homogeneous yet smoothly time-varying dielectric media

We explore the propagation and transformation of electromagnetic waves through spatially homogeneous yet smoothly time-dependent media within the framework of classical electrodynamics. By modelling the smooth transition, occurring during a finite period {\tau}, as a phenomenologically realistic and sigmoidal change of the dielectric permittivity, an analytically exact solution to Maxwell's equations is derived for the electric displacement in terms of hypergeometric functions. Using this solution, we show the possibility of amplification and attenuation of waves and associate this with the decrease and increase of the time-dependent permittivity. We demonstrate, moreover, that such an energy exchange between waves and non-stationary media leads to the transformation (or conversion) of frequencies. Our results may pave the way towards controllable light-matter interaction in time-varying structures.Comment: 5 figure

Interaction of Relativistic Electron-Vortex Beams with Few-Cycle Laser Pulses

We study the interaction of relativistic electron-vortex beams (EVBs) with laser light. Exact analytical solutions for this problem are obtained by employing the Dirac-Volkov wave functions to describe the (monoenergetic) distribution of the electrons in vortex beams with well-defined orbital angular momentum. Our new solutions explicitly show that the orbital angular momentum components of the laser field couple to the total angular momentum of the electrons. When the field is switched off, it is shown that the laser-driven EVB coincides with the field-free EVB as reported by Bliokh et al. [Phys. Rev. Lett. 107, 174802 (2011)]. Moreover, we calculate the probability density for finding an electron in the beam profile and demonstrate that the center of the beam is shifted with respect to the center of the field-free EVB

Synthesis, Characterization, and Study of Catalytic Activity of Chiral Cu(II) and Ni(II) Salen Complexes in the α-Amino Acid C-α Alkylation Reaction

A new family of Cu(II) and Ni(II) salen complexes was synthesized and fully characterized through various physicochemical methods. Their catalytic activity was evaluated in the phase transfer Cα-alkylation reaction of the Schiff bases of D,L-alanine ester and benzaldehyde derivatives. It was found that the introduction of a chlorine atom into the ortho- and para-positions of the phenyl ring of the substrate resulted in an increase in both the chemical yield and the asymmetric induction (ee 66–98%). The highest enantiomeric excess was achieved in the case of a Cu(II) salen complex based on (S,S)-cyclohexanediamine and salicylaldehyde at −20 °C. The occurrence of a bulky substituent in the ligand present in the complexes led to a drastic decrease in ee and chemical yield. For instance, the introduction of bulky substituents at positions 3 and 5 of the phenyl ring of the catalyst resulted in a complete loss of the stereoselectivity control in the alkylation reaction